Answer: BOTH! Also, enemies! (Sometimes?)
So, I've been sucked into a new fandom.
thefourthvine recc'd the first fic in my list below, I loved it, and then I started reading tons of Iron Man/Captain America fics. I watched this year's Captain America and enjoyed it but hadn't seen either Iron Man or Thor, but I suppose it doesn't matter in the end because lots of the fics are based on the comics. According to a friend knowledgeable in comics, that is an eminently slashable pairing from long ago. Since there are different timelines the details (and sometimes the entire premise of the world) are pretty different. I just read a bunch and made a list of the ones I liked.
( list under the cut )
So, I've been sucked into a new fandom.
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( list under the cut )